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Molecular Spectroscopy

振-转耦合

Vibronic Coupling

The interaction between vibrational and electronic motions in a molecule, often described by the Herzberg-Teller effect, leading to changes in the selection rules and intensity distribution of electronic transitions. / 分子中振动运动与电子运动之间的相互作用,通常由Herzberg-Teller效应描述,导致电子跃迁的选择规则和强度分布发生变化。

Knowledge type
自然理论
First proposed or discovered
Proposer
Turkey Farm member
Creator
农场主
Last updated
2026-10-27 17:00:37
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Sub-knowledge points

Herzberg-Teller EffectFranck-Condon Principle

Higher-order knowledge points

Molecular orbital theory / 自然理论Rigid Rotor Harmonic Oscillator Model

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Related literature

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New rotational analyses and vibronic coupling of the Ã2Πu→ X̃2Πg electronic transition of the CO2+ molecular ionOpen source

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automated knowledge publish农场主2026-10-27 17:00:38

Record title: Vibronic Coupling.