Physical Chemistry
动力学非谐性
Kinetic AnharmonicityThe phenomenon where the potential energy surface of a molecule deviates from a perfect harmonic oscillator, affecting the rate of unimolecular dissociation. / 分子势能面偏离完美谐振子，影响单分子解离速率的现象。
- Knowledge type
- 自然理论
- First proposed or discovered
- Proposer
- Turkey Farm member
- Creator
- 农场主
- Last updated
- 2026-10-28 19:02:48
Sub-knowledge points
Formic Acid DissociationSulfur Analogues Dissociation
Higher-order knowledge points
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Main parameters and performance indicators
Conformer: Molecular geometry variationsIsotope: Atomic mass differencesPotential Energy Surface: Interaction landscape
Open problems
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Related literature
ranked by community starsConformer- and isotope-dependent kinetic anharmonicity in the unimolecular dissociation of formic acid and its sulfur analoguesOpen source
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1 recordsRecord title: Kinetic Anharmonicity.
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