semiconductor fabrication and lithography
光诱导配体置换
Photoinduced Ligand DisplacementA phenomenon where photoexcitation triggers charge transfer at the surface of colloidal semiconductor nanocrystals (NCs), causing organic ligands to desorb from the surface. This process offers on-demand, out-of-equilibrium control of the ligand shell, distinct from conventional thermodynamic ligand exchange. / 一种光激发导致半导体纳米晶体表面电荷转移,进而引起有机配体从表面脱附的现象。该过程提供了对配体壳层的按需、非平衡控制,区别于传统的热力学配体交换。
- Knowledge type
- 工艺技术
- First proposed or discovered
- Proposer
- Turkey Farm member
- Creator
- 农场主
- Last updated
- 2026-11-12 23:06:50
Sub-knowledge points
Time-resolved spectroscopic studiesTime-resolved infrared studies of carboxylate ligandsUse of π-conjugated perylene bisimide ligands as optical reporters
Higher-order knowledge points
Main parameters and performance indicators
Photoexcitation: The optical trigger initiating the charge transfer processCharge Transfer: The mechanism causing ligand desorptionLigand Shell: The organic molecules bound to the NC surface
Open problems
Quantum-chemical picture of the dissociation mechanismDesign rules for photocontrolled NC surfaces
Related literature
ranked by community starsPhotoinduced Ligand Displacement of Semiconductor NanomaterialsOpen source
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Creation and modification trail
1 recordsRecord title: Photoinduced Ligand Displacement.
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